Using large eddy simulation, we investigate the combined effect of terrain and surface sensible heat flux (SHF) heterogeneity on the development of afternoon deep moist convection (DMC). We implement an analytically derived, two‐dimensional terrain and SHF variations transformed from a κ− 3 (where κ is the wavenumber) spectrum spanning wavelengths from 32 to 0.2 km. By separately coupling multiscale terrain with a homogeneous SHF field and the multiscale SHF field with flat terrain, we discern the individual impacts of these κ − 3‐spectrum forcings on DMC. Our specific forcing configuration demonstrates that the multiscale terrain had a greater influence on DMC development compared to the multiscale SHF field. While the solely surface SHF heterogeneity forcing results in a wider pool of high relative humidity above the boundary layer, its significance is relatively lower in the mountainous terrain cases due to the shorter interaction time between highly buoyant thermals and the surrounding environment. However, when the multiscale terrain and SHF field are synchronized, DMC develops rapidly within a time frame of 4.5 hr, which is facilitated by enhanced surface buoyancy fluxes, the presence of highly buoyant thermals, and the persistence of mesoscale structures such as near‐surface convergence and mesoscale updrafts. Our study highlights the importance of the synergistic effects between multiscale terrain and surface SHF heterogeneity in DMC development. Additionally, our multiscale analyses of atmospheric variables reveal distinct atmospheric regimes between the pre‐storm and DMC periods. These findings contribute to a better understanding of the complex dynamics involved in the formation of afternoon DMC.